Synthesis of New Monosubstituted Spiropentanes
Chemistry & Chemical Technology
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First published on this website: 28.08.2019 - 20:24
Abstract
Previously known spiropentane derivatives that were studied, were mostly represented by aminoacids. We present a pathway to other derivatives to diversify the extent of known spiropentanes, particularly the respective amidine, carboxylic acid, and hydrazine.
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References
[1] Istomina, N.V. (2008). Small spiroalkanes: ring strain effects and carbon-carbon spin-spin coupling constants. Arkivoc, 12, 68-73. [2] Guan, H.P. (2000) Spiropentane Mimics of Nucleosides: Analogues of 2‘-Deoxyadenosine and 2‘-Deoxyguanosine. Synthesis of All Stereoisomers, Isomeric Assignment, and Biological Activity. The Journal of Organic Chemistry, 65(5),1280-1290. [3] Pellicciari, R. (2002) Spiro[2.2]pentane as a dissymmetric scaffold for conformationally constrained analogues of glutamic acid: focus on racemic 1-aminospiro[2.2]pentyl-1,4-dicarboxylic acids. The Journal of Organic Chemistry, 67(16), 5497-5507. [4] Pesyan N.N. (2017) Decades of synthesis and application of spiro cyclopropanes. Journal of the Iranian Chemical Society, 14(7), 1365-1467. [5] Moss R.A. (2001) Rearrangement Kinetics of Spiropentylchlorocarbene, [3]-Triangulylchlorocarbene, and Related Species. Organic Letters, 3(10), 1439-1442.
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Correct the name "Yurii Dmytric" to "Yurii Dmytriv" in the author field of application form.
Yurii Dmytriv's email address is dmitriv
ukr [dot] net
Updated with spectral data
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