Ionic liquids – application driven synthesis in green chemistry

Green chemistry
Proceedings of the 2nd International Scientific Conference «Chemical Technology and Engineering»: June 24–28, 2019, Lviv: Lviv Polytechnic National University, 2018, pp. 240–242

Authors

First and Last Name Academic degree E-mail Affiliation
Anna Chrobok Ph.D. anna.chrobok [at] polsl.pl Silesian University of Technology
Gliwice, Poland

I and my co-authors (if any) authorize the use of the Paper in accordance with the Creative Commons CC BY license

First publshed on this website: 27.04.2019 - 15:31
Abstract

Ionic liquid-based strategies are presented as a generic approach to tailoring catalysts as a replacement of hazardous acids in industrially-relevant reactions, to generate both environmentally and economically sustainable processes. The possibilities of application of new bronsted and Lewis acidic ionic liquids as catalysts, mainly in the synthesis of fine chemicals: lactones, amides, esters, Diels-Alder cycloadducts and alkilobenzenes are presented.

References

[1] K. Matuszek, A. Chrobok, F. Coleman, K. R. Seddon, M. Swadźba-Kwaśny, “Tailoring ionic liquid catalysts: structure, acidity and catalytic activity of protonic ionic liquids based on anionic clusters, [(HSO4)(H2SO4)x]− (x = 0, 1, or 2),”  Green Chemistry, 16, 3463-3471, 2014.

[2] K. Matuszek, A. Chrobok, P. Latos, M. Markiton, K. Szymańska, A. Jarzębski, M. Swadźba-Kwaśny, “Silica-supported chlorometallate(III) ionic liquids as recyclable catalysts for Diels–Alder reaction under solventless conditions,”  Catalysis Science and Technology, 6, 8129-8137, 2016.

[3] M. Markiton, A. Chrobok, K. Matuszek, K.R. Seddon, M. Swadźba-Kwaśny, “Exceptional activity of gallium(III) chloride and chlorogallate(III) ionic liquids for Baeyer–Villiger oxidation,” RSC Advances, 6, 30460-30467, 2016.

[4] K. Matuszek, S. Coffie, A. Chrobok, M. Swadźba-Kwaśny, “Borenium ionic liquids as catalysts for Diels–Alder reaction: tuneable Lewis superacids for catalytic applications,” Catalysis Science and Technology, 7, 1045-1047, 2017.

[5] K. Matuszek, A. Chrobok, J. M. Hogg, F. Coleman, M. Swadźba-Kwaśny, Friedel–Crafts alkylation catalysed by GaCl3-based liquid coordination complexes,” Green Chemistry, 17, 4255-4262, 2015.

Official paper