Correlation Between Structural Parameters and the Charge of Ln-heteroatom Nuclei in Isostructural Salts Na9[Ln(W5O18)2]·35H2O (Ln = Nd, Eu, Gd, Tb, Dy, Ho, Er)
Chemistry & Chemical Technology
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First published on this website: 13.11.2018 - 10:31
Abstract
Abstract. Comparison of structural parameters in the isostructural sodium heteropoly decatungstolanthanidates(III) with Peacock–Weakley type anion Na9[Ln(W5O18)2]·35H2O (Ln = Nd, Eu, Gd, Tb, Dy, Ho, Er) showed the linear dependences for decreasing of Ln—Ob(W) bond lengths and O…O interatomic distances in the [Ln(W5O18)2]9– anion vs. the charge of Ln–heteroatom nuclei.
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References
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