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Studying on Liquid Phase Cyclohexane Oxidation Enhanced by Oxalic Acid: Pertinent Response by Long-Lasting Challenge

The innovative and nanotechnologies in the chemical and food industries
Proceedings of the 2nd International Scientific Conference «Chemical Technology and Engineering»: June 24–28, 2019, Lviv: Lviv Polytechnic National University, 2018, pp. 195–197

DOI: https://doi.org/10.23939/cte2019.01.195

Authors

First and Last Name Academic degree E-mail Affiliation
Alexander Pokutsa Ph.D. apokutsa [at] ukr.net Department of Physical Chemistry of Fossil Fuels Institute of Physical Organic Chemistry and Coal Chemistry NAS of Ukraine
Lviv, Ukraine
Andriy Zaborovskyi No ntech [at] ukr.net Department of Physical Chemistry of Fossil Fuels Institute of Physical Organic Chemistry and Coal Chemistry NAS of Ukraine
Lviv, Ukraine
Dariya Maksym No maksym_d.s [at] nas.gov.ua Department of Physical Chemistry of Fossil Fuels Institute of Physical Organic Chemistry and Coal Chemistry NAS of Ukraine
Lviv, Ukraine
Pawel Bloniarz Ph.D. bloniarz [at] prz.edu.pl Department of Chemistry, Rzeszow University of Technology
Rzeszow, Poland
Jacques Мuzart Ph.D. jacques.muzart [at] univ-reims.fr Université de Reims Champagne-Ardenne, Institut de Chimie Moléculaire de Reims, UMR 7312, UFR des Sciences Exactes et Naturelles
Reims, France

I and my co-authors (if any) authorize the use of the Paper in accordance with the Creative Commons CC BY license

First published on this website: 17.04.2019 - 16:32
Abstract

A new effective protocol for oxidation of cyclohexane in acetonitrile at 40 °C and atmospheric pressure into cyclohexanol, cyclohexanone and cyclohexyl-hydroperoxide using H2O2 as sustainable oxidant, vanadyl(IV)-acetylacetonate as starting catalyst, oxalic acid and glyoxal as activating additives is presented with some reaction mechanism proposals.

Keywords
Mild oxidationcyclohexanevanadyl(IV)-acetylacetonateH2O2oxalic acidglyoxalprocess activatorsmechanism.
References

[1] J. O. Metzger, M. Eissen, “Concepts on the contribution of chemistry to a sustainable development. Renewable raw materials,” C. R. Chimie, no.7, pp. 569-581, 2004.

First published Full Text (17.04.2019 - 16:32)
Official paper