INTERNATIONAL YOUTH SCIENCE FORUM “LITTERIS ET ARTIBUS”, 24–26 NOVEMBER 2016, 390 LVIV, UKRAINE The first tris-functionalized Anderson-type heteropolytungstate

Nadiia Gumerova1 n.gumerova [at] donnu.edu.ua
Alexander Roller2
Annette Rompel2 annette.rompel [at] univie.ac.at
  1. Department of Inorganic Chemistry, Donetsk National University, Ukraine, Vinnytsia, 600-richchia, 21
  2. Department of Biophysical Chemistry, University of Vienna, Ausria, Vienna, 1090, Althanstrasse 14
Abstract 

Na2[TMA]2[Ni(OH)3W6O18(OCH2)3CCH2OH] represents the first covalent tris-functionalized Anderson-type heteropolytungstate and was characterized by single-crystal X-ray diffraction, electrospray ionization mass spectrometry, TGA and IR spectroscopy. Zeta potential measurements in solutions containing human serum albumin were performed to investigate electrostatic interactions with [Ni(OH)3W6O18(OCH2)3CCH2OH]4–.

References 

[1] M.T. Pope, Inorganic Chemistry Concepts, Vol. 8: Heteropoly and Isopoly Oxometalates, Springer, Berlin, 1983.

[2] Special Issue: Polyoxometalates, ed. by U. Kortz, T. Liu Eur. J. Inorg. Chem., 2013, 10-11, 1556.

[3] A. Dolbecq, E. Dumas, C.R. Mayer and P. Mialane, Chem. Rev., 2010, 110, 6009.

[4] A. Proust, R. Thouvenot and P. Gouzerh, Chem. Commun., 2008, 1837.

[5] B. Hasenknopf, R. Delmont, P. Herson and P. Gouzerh, Eur. J. Inorg. Chem. 2002, 1081.

[6] P.R. Marcoux, B. Hasenknopf, J.Vaissermann and P. Gouzerh Eur. J. Inorg. Chem. 2003, 2406.; (c) Y.-F. Song, D.-L. Long, S.E. Kelly and L. Cronin, Inorg. Chem., 2008, 47, 9137.

[7] C.-G. Lin, W. Chen, D.-L. Long, L. Cronin and Y.-F. Song, Dalton Trans., 2014, 43.

[8] A. Blazevic, E. Al-Sayed, A. Roller, G. Giester and A. Rompel, Chem. Eur. J., 2015, 21, 1.

[9] A. Blazevic, A. Rompel, Coord. Chem. Reviews, 2016, 307, 42.

[10] S.G. Mauracher, C. Molitor, R. Al-Oweini, U Kortz and A. Rompel, Acta Cryst., 2014, F70, 263;

[11] A. Bijelic and A. Rompel, Coord. Chem. Rev., 2015, 299, 22.

[12] C. Molitor, S.G. Mauracher and A. Rompel, Proc. Natl. Acad. Sci. USA, 2016, 113, E1806.

[13] G.M. Rozantsev, S.V. Radio, N.I. Gumerova, V.N. Baumer and O.B. Shishkin, J. Struct. Chem., 2009, 50, 296.