Ionic liquids and supercritical carbon dioxide as solvents for NHPI-catalysed oxidation reactions

Green chemistry
Proceedings of the 2nd International Scientific Conference «Chemical Technology and Engineering»: June 24–28, 2019, Lviv: Lviv Polytechnic National University, 2018, pp. 269–270

Authors

First and Last Name Academic degree E-mail Affiliation
Beata Orlińska Sc.D. beata.orlinska [at] polsl.pl Department of Chemical Organic Technology and Petrochemistry, Silesian University of Technology
Gliwice, Poland
Gabriela Dobras No gabriela.dobras [at] polsl.pl Department of Chemical Organic Technology and Petrochemistry, Silesian University of Technology
Gliwice, Poland
Dawid Lisicki Ph.D. dawid.lisicki [at] polsl.pl Department of Chemical Organic Technology and Petrochemistry, Silesian University of Technology
Gliwice, Poland

I and my co-authors (if any) authorize the use of the Paper in accordance with the Creative Commons CC BY license

First publshed on this website: 29.04.2019 - 13:42
Abstract

Studies on the possibility of application of ionic liquids or scCO2 as solvents in  hydrocarbons oxidation with oxygen in the presence of N-hydrophthalimide  have been reported. Various alkylaromatics (cumene, ethylbenzene, mono- and diisopropylnaphthalene, mono- and diisopropylbiphenyl) and α-methylstyrene were used as starting materials.

References

[1] F. Recupero, C. Punta, “Free Radical Functionalization of Organic Compounds Catalyzed by N-Hydroxyphthalimide”, Org. Chem. Rev., vol. 107, pp. 3800- 3842, 2007.

[2] S. Coseri, “ Phthalimide‐N‐oxyl (PINO) Radical, a Powerful Catalytic Agent: Its Generation and Versatility Towards Various Organic Substrates”, Catal. Rev., vol. 51, pp. 218–292, 2009.

[3] K. Chen, P. Zhang, Y. Wang, H. Li, “Metalfree allylic/benzylic oxidation strategies with molecular oxygen: recent advances and future prospects”, Green Chem., vol. 16, pp. 2344–2374, 2014.

[4] K. Kasperczyk, B. Orlińska, J. Zawadiak, “Aerobic oxidation of cumene catalysed by 4-alkyloxycarbonyl-N-hydroxyphthalimide”, Cent. Eur. J. Chem., vol. 12, pp. 1176–1182, 2014.

[5] G. Dobras, B. Orlińska, “Aerobic oxidation of alkylaromatic hydrocarbons to hydroperoxides catalysed by N-hydroxyimides in ionic liquids as solvents”, Appl. Catal., vol. 561, pp. 59- 67, 2018.

[6] G. Dobras, D. Lisicki, D. Pyszny, B. Orlińska, Badania reakcji utleniającego rozszczepienia α-metylostyrenu tlenem wobec N-hydroksyftalimidu w alternatywnych rozpuszczalnikach” Przem. Chem., vol. 98, no. 4, pp. 610-615, 2019. DOI:10.15199/62.2019.4.19

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