The influence of the coordination properties of metals on the activity of binary catalysts for the oxidation of cyclohexane

Development, energy and resource saving in the chemical and food technologies
4th International Scientific Conference «Chemical Technology and Engineering»: Proceedings – June 26–29th, 2023, Lviv, Ukraine – Lviv: Lviv Polytechnic National University, 2023, pp. 77–79


First and Last Name Academic degree E-mail Affiliation
Anatoliy Ludyn Ph.D. anatolii.m.ludyn [at] Lviv Polytechnic National University
Lviv, Ukraine
Viktor Reutskyy Sc.D. reutskyy [at] Lviv Polytechnic National University
Lviv, Ukraine
Volodymyr Reutskyy Ph.D. gib1986 [at] Lviv Polytechnic National University
Lviv, Ukraine

I and my co-authors (if any) authorize the use of the Paper in accordance with the Creative Commons CC BY license

First published on this website: 21.03.2023 - 18:50

Oxidation processes are one of the groups that play a key role in the modern chemical industry. Oxidation processes usually  are carried out under industrial conditions in the gas phase using heterogeneous catalysts and in the liquid phase using homogeneous catalysts.

The catalyst in any industrial process can be used under the condition that it meets the requirements for activity and selectivity. The cost of raw materials and energy for its production, environmental protection, and utilization of production waste plays a significant role.

This work's main aim was to define the dependencies of efficiency of organic modifiers from the nature of metal in the main catalytic salt. Defining those dependencies will allow us to create a binary catalytic system on the basis of variable valency metal compound [CVVM] and salt of perfluoric sulfur acid [SPSA], with activity and selectivity higher than for industrial catalysts for the oxidation process.


[1]     Ludyn А.М., & Reutskyy, V. V. (2016). Vplyv aminokyslot na process okysnenja cyclogeksanu [Effect of amino acids on oxidation of cyclohexane]. Visnyk NU «Lvivska Polytechnica». Khimija, Tekhnologija recovyn ta zastosuvannja, volume 841. 108-113

[2]     C. Hettige, K. R. R. Mahanama, D. P. Dissanayake. (2001).Cyclohexane oxidation and carbon deposition over metal oxide catalysts.  Chemosphere. Volume 43, Issue 8. 1079.

[3]     R. Christopher, R. Riley, E. Nancy Montgomery, N. Nada Megally, A. Jessica Gunn, L. Shannon Davis .  (2012). Oxidation of Cyclohexane by Transition Metal Oxides on Zeolites . The Open Catalysis Journal. Vol. Р. 8-13.1.

Official paper