A Comparative Study in Metalloorganic Structural Chemistry: the X-ray Crystal Structures of [HB{C3N2H-3,5-(CH3)2}3Zr(OC6H5)3] and [HB{C3N2H-3,5-(CH3)2}3Zr(OC6H4-2-F)3]

The innovative and nanotechnologies in the chemical and food industries
4th International Scientific Conference «Chemical Technology and Engineering»: Proceedings – June 26–29th, 2023, Lviv, Ukraine – Lviv: Lviv Polytechnic National University, 2023, pp. 102–105


First and Last Name Academic degree E-mail Affiliation
Roman Kresinski Ph.D. r.kresinski [at] kingston.ac.uk Kingston University
London, United Kingdom
Dinh-Quoc Tran Ph.D. r.kresinski [at] kingston.ac.uk Kingston University
London, United Kingdom

I and my co-authors (if any) authorize the use of the Paper in accordance with the Creative Commons CC BY license

First published on this website: 17.04.2023 - 23:32

The complexes [ZrL(OC6H4-2-X)3] (L- = HB{3,5-Me2C3HN2}3-, X = H (1), F (2)) are compared structurally with analogous precedents.  Whilst the {LZr}3+ moiety possesses formal or pseudo-C3v symmetry in both cases, the phenoxide ligands adopt a wide variety of attitudes thereto, which appear to be driven mainly by packing forces.


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Official paper


oleksandr.ivashchuk's picture
administrator, reviewer, secretary

Dear authors, please edit your submission - format all the literature on the references list according to APA style: https://www.mtroyal.ca/library/files/citation/apa.pdf

Please add a new version after edition in the comments.

Mon, 04/17/2023 - 23:40
Lesia Sandig-Pr...
researcher, reviewer

The present work contributes to the structural chemistry of Zr-based compounds. The description of the findings and the data for two crystal structures are presented in an understandable and structured way. The work is recommended without further corrections.

Tue, 05/16/2023 - 17:38