Polypyrazolylborate complexes of the lanthanides: structure, optics and materials science
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We report the synthesis and characterisation of monomeric [LnTp2(O2CCH=CHCH3)] (Ln = Ce-Ho, except Pm) and dimeric [LnTp(O2CCH=CHR)2]2 (R = CH3, Ln = Ho-Lu; R =C6H5, Ln = Ce-Yb, except Pm), along with their co-polymerisations with styrene and methyl methacrylate. The structures and some optical properties of the lanthanide complexes and co-polymers are presented.
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