Modeling of Heterogeneous Catalytic Recovery Process of Ketones

Ivanna Skoretska1 ivanna.skoretska [at] gmail.com
Yuriy Beznosyk2 yu_beznosyk [at] ukr.net
  1. Department of Cybernetics of Chemical Technology Processes, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, 37 Peremogy ave., Kyiv, Ukraine, 03056
  2. Department of Cybernetics of Chemical Technology Processes, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, 37 Peremogy ave., Kyiv, Ukraine, 03056
Abstract 

The article considers the mathematical model of the recovery reaction of cyclohexanole by the Meerwein-Ponndorf-Verley mechanism. The activity of the three catalysts in the presence of which the reaction of cyclohexanole recovery took place has been analyzed and selected the most active zeolite for further calculations. With the use of Mathcad 15.0 software the rate constants of investigated reaction has been calculated.

Keywords 
Meerwein-Ponndorf-Verley mechanism
inverse problem of kinetics
rate constant
heterogeneous catalysis
zeolites
References 

[1] I. Skoretska, Yu. Beznosyk, “Modeling of heterogeneous catalytic recovery process of aldehydes and ketones”, Eastern-European Journal of Enterprise Technologies, vol. 3/6 (87), pp. 36-43, 2017.

[2] A. Koreniuk, K. Maresz, J. Mrowiec-Białoń, “Supported zirconium-based continuous-flow microreactor for effective Meerwein-Ponndorf-Verley reduction of cyclohexanone”, Catalysis Communications, vol. 64, pp. 48–51, 2015.

[3] I. Skoretska, “Recovery of anisyl aldehyde through Meerwein-Ponndorf-Verley mechanism”, materials of the XVI All-Ukrainian R&D Students Internet Conference « Science and Technology of the Future», Kyiv, pp.139-140, 27 April – 15 May, 2016.

[4] V. Y. Korobov, V. F. Ochkov, “Khymycheskaia kynetyka: vvedenye s Mathcad”, Maple, MCS, Moscow, Horiachaia lynyia-Telekom, 384 p, 2009