radical polymerization
Synthesis, Properties and Application of Amphiphilic Copolymers Based on Poly(fluoroalkylmethacrylate)s With Terminal Peroxide Group
Polymers with terminal peroxide fragment were synrhesized via radical polymerization of fluoroalkyl methacrylates. Amphiphilic block-copolymers with hydrophilic block of different structure were synthesized by usage of obtained polymers with terminal peroxide group as macroinitiators. Kinethic peculiarities of polymerization were studied on both stages. The strucrure of polymers were confirmed by IR- and NMR-spectroscopy.