Effect of the Reactants Molar Ratio on the Kinetics of Cycloaddition of 2,3-Dimethylbuta-1,3-diene to methylacrylate
The cycloaddition reaction between 2,3-dimethylbuta-1,3-diene and methylacrylate proceeds by the second order kinetics. The rate constants increase with the increase in the excess of one of the reactants. The change in the effective rate constants is described by the Michaelis–Menten equation indicating that the reaction proceeds through the initial equilibrium stage of formation of an intermediate complex which then transforms into the product.