Synthesis of acrylic acid and its esters with Se-containing catalysts

The innovative and nanotechnologies in the chemical and food industries

Proceedings of the 2nd International Scientific Conference «Chemical Technology and Engineering»: June 24–28, 2019, Lviv: Lviv Polytechnic National University, 2018, pp. 143–144

DOI: https://doi.org/10.23939/cte2019.01.143

Authors

First and Last Name	Academic degree	E-mail	Affiliation
Tetiana Kharandiuk	Ph.D.	tetiana.v.kharandiuk [at] lpnu.ua	Lviv Polytechnic National University Lviv, Ukraine
Kok Hui Tan	No	tan [at] dwi.rwth-aachen.de	DWI Leibniz Institute for Interactive Materials e.V Aachen, Germany
Volodymyr Ivasiv	Ph.D.	volodymyr.v.ivasiv [at] lpnu.ua	Lviv Polytechnic National University Lviv, Ukraine
Roman Nebesnyi	Ph.D.	roman.v.nebesnyi [at] lpnu.ua	Lviv Polytechnic National University Lviv, Ukraine
Andrij Pich	Sc.D.	pich [at] dwi.rwth-aachen.de	DWI Leibniz Institute for Interactive Materials e.V Aachen, Germany

I and my co-authors (if any) authorize the use of the Paper in accordance with the Creative Commons CC BY license

First published on this website: 18.03.2019 - 16:31

Abstract

Se-containing catalysts of organic and inorganic nature were explored for the synthesis of acrylic acid and its esters in different solvents. Newly synthesized Se-containing microgel catalyst shown the best catalytic performance. With microgel catalyst different acrylate monomers can be produced with high yield simply by varying solvent nature

Keywords

acrolein acrylic acid methyl acrylate ethyl acrylate butyl acrylate Se-microgel catalysts

References

[1] R. Beerthuis, G. Rothenberg, N. R. Shiju, “Catalytic routes towards acrylic acid, adipic acid and ε-caprolactam starting from biorenewables,” Green Chemistry, vol. 17, no. 3, March, pp. 1341-1361, 2015.

[2] K. Weissermel and H.-J. Arpe, Industrial Organic Chemistry. Weinheim: WILEY-VCH Verlag GmbH & Co. KGaA, 2003.

[3] C. Marsden, E. Taarning, D. Hansen, L. Johansen, S. K. Klitgaard, K. Egeblad and C. H. Christensen, “Aerobic oxidation of aldehydes under ambient conditions using supported gold nanoparticle catalysts,” Green Chemistry, vol. 10, no. 2, Feb., pp. 168-170, 2008.

[4] K. Yu. Koltunov, V. I. Sobolev, V. M. Bondareva, “Oxidation, oxidative esterification and ammoxidation of acrolein overmetal oxides: Do these reactions include nucleophilic acyl substitution?,” Catalysis Today, vol. 279, no. 1, Jan., pp. 90-94, 2017.

[5] L. Zhou, B. Donga, S. Tang, H. Ma, C. Chen, X. Yang, J. Xu, “Sulfonated carbon catalyzed oxidation of aldehydes to carboxylic acids by hydrogen peroxide,” Journal of Energy Chemistry, vol. 22, no. 4, Jul., pp. 659-664, 2013.

[6] Y. Rangraz, F. Nemati, A. Elhampour, “Diphenyl diselenide immobilized on magnetic nanoparticles: A noveland retrievable heterogeneous catalyst in the oxidation of aldehydes under mild and green conditions,” Journal of Colloid and Interface Science, vol. 509, no. 1, Jan., pp. 485-494, 2018.

First published Full Text (18.03.2019 - 16:31)

Official paper